简历:
2022.10—至今 教授, 四川大学 化学学院
2019.06—至今 四川大学“双百人才工程”百人计划
2016.10—2022.09 副教授, 四川大学 化学学院
2014.01—2016.09 讲师,红宝石官方网站hbs160
2013.06—2013.12 研究助理,红宝石官方网站hbs160杨成教授课题组
2008.09—2013.06 博士,大连理工大学精细化工国家重点实验室
2004.09—2008.07 学士,大连理工大学化工学院
主要研究方向:
分子光化学与光物理;光子能量上转换;超分子光化学;主客体作用;分子识别与传感;金属配合物等
主要工作业绩:
主要从事分子光化学与光物理、超分子化学方面的研究工作,重点研究通过分子光物理性质优化与超分子组装的方法来控制三线态-三线态湮灭上转换、光化学反应和分子传感等有机光化学与光物理行为。目前共发表sci研究论文80余篇,作为第一作者或通讯作者发表论文56篇,单篇最高被引次数200余次。作为项目负责人主持国家自然科学基金面上项目(2项)、自然科学基金青年项目等省部级以上项目10余项.
主持项目:
1. 国家自然科学基金面上项目,22171194,基于超分子自组装的敏化室温磷光与TTA上转换荧光的可控调节,2022.1-2025.12,76.2万,项目负责人
2. 国家自然科学基金面上项目,21971169,超分子组装提高TTA上转换效率的研究,2020.1-2023.12,76.8万,项目负责人
3. 四川省科技厅 国际科技合作计划,2022YFH0095,超分子自组装提高固相TTA上转换发光的研究,2022.01-2024.12,项目负责人
4. 四川大学青年科技学术带头人培育项目 35万,项目负责人
5. 四川省科技厅,2019YJ0090,超分子功能化三线态湮灭剂的合成与应用,2019.01-2020.12,10万,项目负责人
6. 四川大学创新火花项目,2018SCUH0014,新型超分子三线态湮灭剂的组装行为对上转换发光的影响,2018.01-2020.12,22万,项目负责人
7. 中国博士后面上基金,2017M612957,超分子自组装效应在三重态湮灭上转换中的应用研究,2017.1—2018.5,5 万,项目负责人
8. 四川省博士后科研项目特别资助(一等),10 万,项目负责人
9. 中国博士后基金特别资助,2018T110968,利用超分子组装体实现固相高效三重态湮灭上转换的研究,2018.02-2019.02, 15 万,项目负责人
10. 大连理工大学精细化工国家重点实验室开放课题,KF1508, 复合超分子主体用于提高三重态湮灭上转换效率的研究,2015.12-2018.03,5 万,主持
11. 国家自然科学基金-青年科学基金,21402129,超分子作用诱导的高效三重态湮灭光子上转换体系的研究,2015.01-2017.12,25万,项目负责人
12. 四川大学青年教师科研启动基金,2014SCU11051,三重态光敏剂与受体一体化的高效TTA上转换体系的研究,2014.04-2015.12,9万,项目负责人
主要社会兼职:
1.《Chin. Chem. Lett.》编委;中国感光协会青年理事;《Current Opinion in Green and Sustainable Chemistry》专刊编辑
发表论文:
1. Wei, L.; Fan, C.; Rao, M.; Gao, F.; He, C.; Sun, Y.; Zhu, S.; He, Q.; Yang, C.; Wu, W.*, Triplet-Triplet Annihilation Upconversion in Laponite/PVP Nanocomposites: Absolute Quantum Yields up to 23.8% at Solid-State and Application to Anti-counterfeiting. Materials Horizons, 2022, 9, 3048-3056.
2. Wei, X.; Ji, J.; Nie, Y.; Tang, L.; Rao, M.; Wang, X.; Wu, W.*; Su, D.; Zhong, Z.; Yang, C.*, Synthesis of cyclodextrin derivatives for enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate. Nat. Protoc. 2022, 17, 2494-2516.
3. Ji, J.; Wei, X.; Wu, W.*; Fan, C.; Zhou, D.; Kanagaraj, K.; Cheng, G.; Luo, K.; Meng, X. G.; Yang, C.*, The More the Slower: Self-Inhibition in Supramolecular Chirality Induction, Memory, Erasure, and Reversion. J. Am. Chem. Soc. 2022, 144, 1455-1463.
4. Zhang, D.; Liang, W.; Yi, J.; Chen, J.; Lv, Y.; Zhao, T.; Xiao, C.; Xie, X.; Wu, W*.; Yang, C*., Photochemical graft of γ-cyclodextrin’s interior leading to in-situ charge-transfer complexes with unusual regioselectivity and its application in 3D photo-printing. Science China Chemistry 2022, 65, 1149-1156.
5. Yu, X.; Gao, F.; Zhao, W.; Lai, H.; Wei, L.; Yang, C.; Wu, W.*, BODIPY-conjugated bis-terpyridine Ru(II) complexes showing ultra-long luminescence lifetimes and applications to triplet-triplet annihilation upconversion. Dalton Trans 2022, 51, 9314-9322.
6. Tu, C.; Wu, W.*; Liang, W.; Zhang, D.; Xu, W.; Wan, S.; Lu, W.; Yang, C.*, Host–Guest Complexation-Induced Aggregation Based on Pyrene-Modified Cyclodextrins for Improved Electronic Circular Dichroism and Circularly Polarized Luminescence. Angew. Chem. Int. Ed. 2022, e202203541.
7. Rao, M.; Fan, C.; Ji, J.; Liang, W.; Wei, L.; Zhang, D.; Yan, Z.; Wu, W.*; Yang, C.*, Catalytic Chiral Photochemistry Sensitized by Chiral Hosts-Grafted Upconverted Nanoparticles. ACS Appl Mater Interfaces 2022, 14, 21453-21460.
8. Yu, X.; Wan, S.; Wu, W.*; Yang, C.*; Lu, W., gamma-Cyclodextrin-based [2]rotaxane stoppered with gold(I)-ethynyl complexation: phosphorescent sensing for nitroaromatics. Chemical communications 2022, 58, 6284-6287.
9. Yao, J.; Wu, W.*; Xiao, C.; Su, D.; Zhong, Z.; Mori, T.; Yang, C*., Overtemperature-protection intelligent molecular chiroptical photoswitches. Nat Commun 2021, 12 (1), 2600.
10. Yu, X.; Wu, W.*; Zhou, D.; Su, D.; Zhong, Z.; Yang, C., Bisindole [3]arenes—Indolyl Macrocyclic Arenes Having Significant Iodine Capture Capacity. CCS Chemistry 2021, 1945-1953.
11. Supramolecular spectral/visual detection of urinary polyamines through synergetic/competitive complexation with gamma-CD and CB[7] Tian Haoyu; Yu Xingke; Yao Jiabin; Gao Guowei; Wu Wanhua*; Yang Cheng*. Chem. Commun. 2021, 57 (14), 1806-1809.
12. Guest-Binding-Induced Interhetero Hosts Charge Transfer Crystallization: Selective Coloration of Commonly Used Organic Solvents. Mi Yan; Ma Jingyu; Liang Wenting; Xiao Chao; Wu Wanhua*; Zhou Dayang; Yao Jiabin; Sun Wenjia; Sun Junliang*; Gao Guowei; Chen Xiaochuan; Chruma J. Jason; Yang Cheng* J. Am. Chem. Soc. 2021, 143 (3), 1553-1561.
13. Liu, C.; Yao, J.; Xiao, C.; Zhao, T.; Selvapalam, N.; Zhou, C.; Wu, W.*; Yang, C.*, Electrochemiluminescent Chiral Discrimination with a Pillar[5]arene Molecular Universal Joint-Coordinated Ruthenium Complex. Org Lett 2021, 23 (10), 3885-3890.
14. Trace mild acid-catalysed Z → E isomerization of norbornene-fused stilbene derivatives: intelligent chiral molecular photoswitches with controllable self-recovery. Hao Taotao; Yang Yongsheng; Liang Wenting; Fan Chunying; Wang Xin; Wu Wanhua*; Chen Xiaochuan; Fu Haiyan*; Chen Hua; Yang Cheng* Chemical science 2021, 12 (7), 2614-2622.
15. A dendritic DPA annihilator—syntheses, photophysical properties and application for co-assembling enhanced triplet-triplet annihilation upconversion.Guo Qian; Li Guojuan; Rao Ming; Wei Lingling; Gao Fanrui; Wu Wanhua*; Yang Qingshan*; Cheng Guo*; Yang Cheng* Dyes and Pigments 2020, 182, 108643
16. pH-Controlled Chirality Inversion in Enantiodifferentiating Photocyclodimerization of 2-Antharacenecarboxylic Acid Mediated by gamma-Cyclodextrin Derivatives. Kanagaraj Kuppusamy; Liang Wenting; Rao Ming; Yao Jiabin; Wu Wanhua*; Cheng Guo; Ji Jiecheng; Wei Xueqing; Peng Chao; Yang Cheng*. Org Lett 2020, 22 (14), 5273-5278.
17. Synergetic effects in the enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by beta-cyclodextrin-pillar[5]arene-hybridized hosts. Ji Jiecheng; Wu Wanhua*; Wei Xueqing; Rao Ming; Zhou Dayang; Cheng Guo; Gong Qiyong; Luo Kui*; Yang Cheng* Chemical communications 2020, 56 (46), 6197-6200.
18. Pyrene-tiaraed pillar[5]arene: Strong intramolecular excimer emission applicable for photo-writing. Peng Chao; Liang Wenting; Ji Jiecheng; Fan Chunying; Kanagaraj Kuppusamy; Wu Wanhua*; Cheng Guo; Su Dan; Zhong Zhihui; Yang Cheng* Chinese Chemical Letters 2021, 32 (1), 345-348.
19. A Quinoline-Appended Cyclodextrin Derivative as a Highly Selective Receptor and Colorimetric Probe for Nucleotides. Kanagaraj Kuppusamy; Xiao Chao; Rao Ming; Fan Chunying; Borovkov Victor*; Cheng Guo; Zhou Dayang; Zhong Zhihui; Su Dan; Yu Xingke; Yao Jiabin; Hao Taotao; Wu Wanhua*; Chruma J. Jason; Yang Cheng* iScience 2020, 23, 100927.
20. Fulleropillar[4]arene: The Synthesis and Complexation Properties. Mi Yan; Yao Jiabin; Ma Jingyu; Dai Ling; Xiao Chao; Wu Wanhua*; Yang Cheng*, Org Lett 2020, 22, 2118-2123. (封面论文)
21. Supramolecular enantiomeric and structural differentiation of amino acid derivatives with achiral pillar[5]arene homologs. Ji Jiecheng; Li Yizhou; Xiao Chao; Cheng Guo; Luo Kui; Gong Qiyong; Zhou Dayang; Chruma J. Jason; Wu Wanhua*; Yang Cheng* Chem. Commun. 2020, 56, 161-164
22. Efficient Triplet-Triplet Annihilation Upconversion with an Anti-Stokes Shift of 1.08 eV Achieved by Chemically Tuning Sensitizers. Chunying Fan, Lingling Wei, Tong Niu, Ming Rao, Guo Cheng, Jason J. Chruma, Wanhua Wu*, and Cheng Yang*. J. Am. Chem. Soc. 2019, 141, 15070−15077. DOI:10.1021/jacs.9b05824
23. Precise Manipulation of Temperature‐Driven Chirality Switching of Molecular Universal Joints through Solvent Mixing. Chunying Fan, Jiabin Yao, Guojuan Li, ChengGuo, WanhuaWu*, Dan Su, Zhihui Zhong, Dayang Zhou, Yuliang Wang, Jason J. Chruma, and Cheng Yang*. Chem. Eur. J. 2019, 25, 12526-12537. DOI: 10.1002/chem.201902676
24. Effects of Temperature and Host Concentration on the Supramolecular Enantiodifferentiating [4 + 4] Photodimerization of 2-Anthracenecarboxylate through Triplet-Triplet Annihilation Catalyzed by Pt-Modified Cyclodextrins. Ming Rao, Wanhua Wu*, Cheng Yang*. Molecules, 2019, 24, 1502. DOI: https://doi.org/10.3390/molecules24081502
25. Resolution and Racemization of a Planar-Chiral A1/A2-Disub-stituted Pillar[5]arene. Chao Xiao, Wenting Liang, Wanhua Wu*, Kuppusamy Kanagaraj, Yafen Yang, Ke Wen, Cheng Yang*. Symmetry, 2019, 11, 773. DOI: https://www.mdpi.com/2073-8994/11/6/773
26. Synthesis, enantioseparation and photophysical properties of planar-chiral pillar [5] arene derivatives bearing fluorophore fragments. Guojuan Li, Chunying Fan, Guo Cheng, Wanhua Wu* and Cheng Yang*. Beilstein J. Org. Chem. 2019, 15, 1601-1611. DOI:10.3762/bjoc.15.164
27. Assembly-enhanced triplet-triplet annihilation upconversion in the aggregation formed by Schiff-base Pt (II) complex grafting-permethyl-β-CD and 9, 10-diphenylanthracence dimer. Hongxia Lai, Ting Zhao, Yurong Deng, Chunyin Fan, Wanhua Wu*, Cheng Yang*. Chin. Chem. Lett. 2019, 30, 1979-1983.
28. A BODIPY- based near infrared fluorescent probe for Fe3+ in water. Jiecheng Ji, Syama S. Chereddy, Yi Ren, Xingming Chen, Dan Su, Zhihui Zhong, Tadashi Mori, Yoshihisa Inoue*, Wanhua Wu* and Cheng Yang*, J. Photochem. Photobiol. A 2018, 355, 78. DOI.org/10.1016/j.jphotochem.2017.10.043
29. Supramolecular Photochirogenesis Driven by Higher-Order Complexation: Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate to Slipped Cyclodimers via a 2: 2 Complex with β-Cyclodextrin. Xueqin Wei#, Wanhua Wu#, Ryohei Matsushita#, Zhiqiang Yan#, Dayang Zhou, Jason J. Chruma, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue*, and Cheng Yang*., J. Am. Chem. Soc., 2018, 140, 3959. DOI: 10.1021/jacs.7b12085
30. 聚集体中的三重态-三重态湮灭上转换. 范春英; 伍晚花*; 杨成*, 有机化学, 2018, 38, 1377. DOI: 10.6023/cjoc201712034.
31. Enhanced Chiral Recognition by γ-Cyclodextrin-Cucurbit [6] uril-Cowheeled [4] Pseudorotaxanes. Ling Dai#, Wanhua Wu#, Wenting Liang, Wentong Chen, Xingke Yu, Jiecheng Ji, Chao Xiao and Cheng Yang. Chem. Commun. 2018, 54, 2643-2646. DOI: 10.1039/c8cc00840j
32. Switched enantioselectivity by solvent components and temperature in photocyclodimerization of 2-anthracenecarboxylate with 6A,6X-diguanidio−γ-cyclodextrins. Jigao Yi, Wenting Liang, Xueqin Wei, Jiabin Yao, Zhiqiang Yan, Dan Sua, Zhihui Zhong, Guowei Gao, Wanhua Wu*, Cheng Yang* Chin. Chem. Lett., 2018, 29, 87-90. DOI: 10.1016/j.cclet.2017.05.004
33. Photocatalytic Supramolecular Enantiodifferentiating Dimerization of 2‑Anthracenecarboxylic Acid through Triplet−Triplet Annihilation. Ming Rao, Kuppusamy Kanagaraj, Chunying Fan, Jiecheng Ji, Chao Xiao, Xueqin Wei, Wanhua Wu* and Cheng Yang*, Org. Lett. 2018, 20, 1680−1683. DOI: 10.1021/ acs.orglett.8b00520
34. Supramolecular Assembly‐Improved Triplet–Triplet Annihilation Upconversion in Aqueous Solution. Wei Xu, Wenting Liang, Wanhua Wu*, Chunying Fan, Ming Rao, Dan Su, Zhihui Zhong, Cheng Yang* Chem. Eur. J., 2018, 24, 16677. DOI: 10.1002/chem.201804001
35. Induced chirality sensing through formation and aggregation of the chiral imines double winged with pyrenes or perylenes. Jianlin Wu, Wenting Liang, Tong Niu, Wanhua Wu*, Dahui Zhou, Chunying Fan, Jiecheng Ji, Guowei Gao*, Jian Meng, Cheng Yang* Chem. Commun. 2018, 54, 9206. DOI:10.1039/C8CC03660H
36. Temperature-Driven Planar Chirality Switching of a Pillar[5]arene-Based Molecular Universal Joint. Jiabin Yao#, Wanhua Wu#, Wenting Liang, Yujun Feng, Dayang Zhou, Jason J. Chruma, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue, Cheng Yang* Angew. Chem., Int. Ed. 2017, 56 (24), 6869-6873.
37. Enhanced Triplet-Triplet Energy Transfer and Upconversion Fluorescence through Host-Guest Complexation. Chunying Fan#, Wanhua Wu#, Jason J. Chruma, Jianzhang Zhao, Cheng Yang, J. Am. Chem. Soc. 2016, 138, 15405-15412.
38. Recent advance of photochromic diarylethenes-containing supramolecular systems. Chao Xiao, Weiye Zhao, Dayang Zhou, Yan Huang, Ye Tao, Wanhua Wu*, Cheng Yang*, Chin. Chem. Lett. 2015, 26, 817-824.
39. Red-light excitable fluorescent platinum(ii) bis(aryleneethynylene) bis(trialkylphosphine) complexes showing long-lived triplet excited states as triplet photosensitizers for triplet-triplet annihilation upconversion. Wanhua Wu, Jianzhang Zhao, Jifu Sun, Ling Huang, Xiuyu Yi, J. Mater. Chem. C 2013, 1 (4), 705-716.
40. Observation of the room temperature phosphorescence of Bodipy in visible light-harvesting Ru(ii) polyimine complexes and application as triplet photosensitizers for triplet-triplet-annihilation upconversion and photocatalytic oxidation. Wanhua Wu, Jifu Sun, Xiaoneng Cui, Jianzhang Zhao*, J. Mater. Chem. C 2013, 1 (30), 4577-4589.
41. Red-light-absorbing diimine Pt(II) bisacetylide complexes showing near-IR phosphorescence and long-lived 3IL excited state of Bodipy for application in triplet-triplet annihilation upconversion. Wanhua Wu, Lianlian Liu, Xiaoneng Cui, Caishun Zhang, Jianzhang Zhao. Dalton Trans. 2013, 42 (40), 14374-14379.
42. Hetero Bodipy-dimers as heavy atom-free triplet photosensitizers showing a long-lived triplet excited state for triplet-triplet annihilation upconversion. Wanhua Wu, Xiaoneng Cui, Jianzhang Zhao*, Chem. Commun. 2013, 49 (79), 9009-9011.
43. Light-Harvesting Fullerene Dyads as Organic Triplet Photosensitizers for Triplet-Triplet Annihilation Upconversions. Wanhua Wu, Jianzhang Zhao*, Jifu Sun, Song Guo. J. Org. Chem. 2012, 77 (12), 5305-5312.
44. Long-lived room-temperature near-IR phosphorescence of BODIPY in a visible-light-harvesting N(caret)C(caret)N PtII-acetylide complex with a directly metalated BODIPY chromophore. Wanhua Wu, Jianzhang Zhao*, Huimin Guo, Jifu Sun, Shaomin Ji, Zilong Wang, Chem. - Eur. J. 2012, 18 (7), 1961-1968.
45. Ruthenium(II)-Polyimine-Coumarin Light Harvesting Molecular Arrays: Design Rationale and Application for Triplet-Triplet-Annihilation-Based Upconversion. Wanhua Wu, Shaomin Ji, Wenting Wu, Jinyin Shao, Huimin Guo, Tony D. James, Jianzhang Zhao*, Chem. - Eur. J. 2012, 18 (16), 4953-4964.
46. Development of triplet-triplet annihilation upconversion. Wanhua Wu, Song Guo, Jianzhang Zhao* Zhongguo Kexue: Huaxue 2012, 42 (10), 1381-1398.
47. Tuning the emission property of carbazole-caped cyclometalated platinum(II) complexes and its application for enhanced luminescent oxygen sensing. Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Jianzhang Zhao*. J. Organomet. Chem. 2011, 696 (11-12), 2388-2398.
48. Tuning the emissive triplet excited states of platinum(II) Schiff base complexes with pyrene, and application for luminescent oxygen sensing and triplet-triplet-annihilation based upconversions. Wanhua Wu, Jifu Sun, Wenting Wu, Jianzhang Zhao*, Huimin Guo. Dalton Trans. 2011, 40 (43), 11550-11561.
49. Organic Triplet Sensitizer Library Derived from a Single Chromophore (BODIPY) with Long-Lived Triplet Excited State for Triplet-Triplet Annihilation Based Upconversion. Wanhua Wu, Huimin Guo, Wenting Wu, Shaomin Ji, Jianzhang Zhao*. J. Org. Chem. 2011, 76 (17), 7056-7064.
50. Tuning the emission properties of cyclometalated platinum(II) complexes by intramolecular electron-sink/arylethynylated ligands and its application for enhanced luminescent oxygen sensing. Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Lina Chi, Jinyin Shao, Jianzhang Zhao*.J. Mater. Chem. 2010, 20 (43), 9775-9786.
51. Enhanced luminescence oxygen sensing property of Ru(II) bispyridine complexes by ligand modification. Wanhua Wu, Shaomin Ji, Wenting Wu, Huimin Guo, Xin Wang, Jianzhang Zhao*, Zhonggang Wang, Sens. Actuators, B 2010, 149 (2), 395-406.